Wednesday, February 14, 2007

Silver – The Relationship between Purity, Carats and Fineness

The purity or fineness of silver alloys is now described using the millesimal system in most countries. This system uses a number to represent the purity of the alloy. The number described purity in parts per thousand.

Previous to the millesimal system, the fineness of silver was expressed in carats. While the fineness of silver alloys must be stamped or hallmarked into pieces, the millesimal value is generally compulsory and the carat value now optional.

Table 1. Some of the most common fineness denominations used.

Fineness

Common Name

Purity (wt.%)

999

Fine or pure silver

99.9

958

Brittania

95.8

925

Sterling silver

92.5

800

Jewellery silver

80

Pure silver is typically very soft and malleable, hence it is commonly alloyed to increase its hardness and durability for applications such as jewellery. It is typically alloyed with copper in this instance, with sterling silver being one of the most popular alloys, containing 7.5% copper. Copper is used as it is a hardening agent and does not discolour the silver.

Gold - Properties and Uses – Supplier Data by Goodfellow

This metal has been known since prehistoric times.

Gold is a soft metal with a characteristic yellow colour. It is the most malleable and ductile of any element. It is unaffected by air, water, alkalis and acids, with the exception of “aqua regia”, HNO3/HCl. The fact that it is chemically unreactive means that it is often found in its natural state. It is a good thermal and electrical conductor and has excellent reflective properties to both light and infrared. It has an abundance in the earth’s crust of 0.0011 ppm.

Most of the metal is retained for use as bullion reserves, but some is used within the electronics and jewellery industries, where it is frequently alloyed with other elements to improve the mechanical properties of the metal (e.g. copper and silver). Other uses for the metal are as a heat reflecting coating for glass as well as as a decorative medium.

Key Properties

Atomic Properties

Atomic number

79

Atomic radius - Goldschmidt ( nm )

0.144

Atomic weight ( amu )

196.9665

Crystal structure

Face centred cubic

Electronic structure

Xe 4f14 5d10 6s1

Photo-electric work function ( eV )

4.8

Thermal neutron absorption cross-section ( Barns )

98.8

Valences shown

1,3

Ionisation Potential

No.

eV

1

9.22

2

20.5

Natural Isotope Distribution

Mass No.

%

197

100

Electrical Properties

Temperature coefficient ( K-1 )

0.0040 @ 0-100

Electrical resistivity ( µOhm.cm )

2.20 @ 20

Thermal emf against Pt (cold 0°C - hot 100°C) ( mV )

+0.74

Mechanical Properties

Material condition

Soft

Hard

Polycrystalline

Bulk modulus ( GPa )

171

Hardness - Vickers

20-30

60

Poisson's ratio

0.42

Tensile modulus ( GPa )

78.5

Tensile strength ( MPa )

130

220

Yield strength ( MPa )

205

Physical Properties

Boiling point (°C )

3080

Density ( g.cm-3 )

19.30 @ 20

Melting point (°C )

1064.4

Thermal Properties

Coefficient of thermal expansion ( x10-6 K-1 )

14.1 @ 0-100

Latent heat of evaporation ( J.g-1 )

1738

Latent heat of fusion ( J.g-1 )

64.9

Specific heat ( J.K-1.kg-1 )

129 @ 25

Thermal conductivity ( W.m-1.K-1 )

318 @ 0-100


Platinum Gauze 52 Mesh Woven from 0.1mm (0.04in) Wire - 99.9% Purity from Alfa Aesar

Platinum is a transition metal element. Mostly noted as a precious metal used in jewellery, its extremely low reactivity and thermal stability see it used in laboratory ware.

Properties

Property

Value

Atomic Number

78

Atomic Mass

195.09

Density

21.09g/cm3

Melting Point

1768˚C

Boiling Point

3825˚C

CAS Number

7440-06-4

Available Sizes

· 25x25mm

· 50x50mm

· 75x75mm

· 100x100mm

Open area: 62.7%; Width of opening: 0.015in

Platinum Wire 0.1mm (0.04in) Diameter Annealed - 99.95% Purity from Alfa Aesar

Platinum is a transition metal element. Mostly noted as a precious metal used in jewellery, its extremely low reactivity and thermal stability see it used in laboratory ware.

Properties

Property

Value

Atomic Number

78

Atomic Mass

195.09

Density

21.09g/cm3

Melting Point

1768˚C

Boiling Point

3825˚C

CAS Number

7440-06-4

Available Sizes

· 5cm

· 25cm

· 100cm

Approximately 16.8g/m

Dosilac Conductive Silver Spray Paint

Dosilac is a new conductive silver spray paint from Ami Doduco. It combines speed, ease and economy for the application of metal coatings to non-conducting surfaces.

The purpose designed nozzle makes dosing easy and gives a uniform coating.

Spraying is economical compared to brushing as it is able to cover ten times the surface area with the same amount of material. Furthermore, the paint does not dry in the can meaning that there are lower losses and the material remains more consistent.

The silver spray paint provides a better alternative to traditional silver conductive paints that require application by brush. They are suited to applications including, but certainly not limited to:

· Dentistry

· Jewellery

· Amateur electronics

· Repairing printed circuit boards

· Electromagnetic shielding

· Rear windscreen heaters